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水的辐射化学简史

A short history of the radiation chemistry of water.

作者信息

Jonah C D

机构信息

Chemistry Division, Argonne National Laboratory, Illinois 60439, USA.

出版信息

Radiat Res. 1995 Nov;144(2):141-7.

PMID:7480640
Abstract

The first hundred years of radiation studies have greatly clarified the chemical processes that are induced by radiation. While the fundamental ionization processes are similar in all systems, properties of the medium such as phase, polarity and composition can greatly affect the chemistry. In all systems, one needs to understand what chemical species are formed, what the internal energies are, how they are dispersed spatially, and what reactions can occur. In this review, the progress that has been made in understanding the chemistry that occurs after a radiolysis event for liquid water is outlined as an example of how progress has been made in radiation chemistry.

摘要

辐射研究的头一百年极大地阐明了由辐射引发的化学过程。虽然基本的电离过程在所有系统中都是相似的,但介质的性质,如相、极性和组成,会对化学过程产生很大影响。在所有系统中,人们需要了解形成了哪些化学物种、它们的内能是多少、它们如何在空间中扩散以及会发生哪些反应。在本综述中,作为辐射化学取得进展的一个例子,概述了在理解液态水辐解事件后发生的化学过程方面所取得的进展。

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