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使用量化最大熵方法优化电子顺磁共振波谱信息。

The use of quantified maximum entropy methods for optimising information from electron paramagnetic resonance spectroscopy.

作者信息

Goodman B A, Glidewell S M, Skilling J

机构信息

Scottish Crop Research Institute, Invergowrie, Dundee.

出版信息

Free Radic Res. 1995 Apr;22(4):337-47. doi: 10.3109/10715769509145646.

Abstract

A quantified maximum entropy method is applied to the optimisation of analytical information from EPR spectra of free radicals. Statistically meaningful errors are produced for the positions and intensities of all spectral peaks and considerable improvements in sensitivity compared with conventional spectral enhancement procedures are obtained with measurements of the intensities of spectra of known radicals.

摘要

一种定量最大熵方法被应用于优化自由基电子顺磁共振谱的分析信息。对于所有光谱峰的位置和强度产生了具有统计学意义的误差,并且通过测量已知自由基的光谱强度,与传统光谱增强程序相比,灵敏度有了显著提高。

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