2-(3',4'-二甲氧基肉桂基)-2-甲基环戊烷-1,3-二酮酵母还原产物的绝对立体化学
Absolute stereochemistry of yeast reduction products from 2-(3',4'-dimethoxy-cinnamyl)-2-methylcyclopentane-1,3-dione.
作者信息
Sakakibara M, Ogawa-Uchida A
机构信息
Pharmaceutical Research Laboratories, Kirin Brewery Co., Ltd., Gunma, Japan.
出版信息
Biosci Biotechnol Biochem. 1995 Jul;59(7):1300-3. doi: 10.1271/bbb.59.1300.
PMID:7670191
Abstract
The absolute stereochemistry of yeast reduction products 2s and 2a from 2-(3',4'-dimethoxy-cinnamyl)-2-methylcyclopentane-1,3-dione (1) was investigated. The results from several spectral studies and chemical correlations enabled their absolute configurations to be concluded as (2S,3S) and (2R,3S), respectively.
摘要
对2-(3',4'-二甲氧基肉桂基)-2-甲基环戊烷-1,3-二酮(1)的酵母还原产物2s和2a的绝对立体化学进行了研究。几项光谱研究和化学关联的结果表明，它们的绝对构型分别为(2S,3S)和(2R,3S)。
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