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固定化柿子单宁对金的吸附与回收

Uptake and recovery of gold by immobilized persimmon tannin.

作者信息

Nakajima A, Sakaguchi T

机构信息

Department of Chemistry, Miyazaki Medical College, Japan.

出版信息

J Chem Technol Biotechnol. 1993;57(4):321-6. doi: 10.1002/jctb.280570405.

Abstract

Some attempts were made to recover gold from aqueous systems using immobilized persimmon tannin. This adsorbent adsorbed gold from solutions containing hydrogen tetrachloroaurate (III) with high efficiency, whereas there was minimal adsorption from solutions containing gold(I) sodium thiomalate and sodium dicyanoaurate(I). The adsorption of gold was rapid, and was affected by the pH of the solution, temperature, external gold concentration and amount of adsorbent. Adsorbed gold was easily desorbed with 1 mol dm-3 thiourea solution, indicating that immobilized persimmon tannin can be repeatedly re-used for the recovery of gold using adsorption-desorption cycles.

摘要

人们尝试使用固定化柿子单宁从水体系中回收金。这种吸附剂能高效地从含有氯金酸(III)的溶液中吸附金,而从含有硫代苹果酸金(I)和氰化亚金钠(I)的溶液中的吸附量极少。金的吸附迅速,并且受溶液pH值、温度、外部金浓度和吸附剂用量的影响。吸附的金很容易用1 mol dm-3硫脲溶液解吸,这表明固定化柿子单宁可通过吸附-解吸循环重复用于金的回收。

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