Corrections to the cross-polarization dynamics in solids. The effect of nonsecular terms of heteronuclear dipolar interaction on cross-relaxation.

The dynamic theory of cross-polarization in solids is modified by considering the contribution of the nonsecular terms of the heteronuclear dipolar interaction Hamiltonian in the laboratory frame to cross-relaxation. This contribution is evaluated numerically and confirmed experimentally. It is shown that these nonsecular terms may play a considerable role in cross-relaxation in many systems, especially in those with fast internal molecular motion. The complication in the cross-polarization process is further revealed.