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[一种用于测定聚氯乙烯粉尘和颗粒中残留单体含量的快速检测方法]

[A rapid test for determining the content of residual monomer in polyvinyl chloride dust and granulate].

作者信息

Vardev P, Rizov I

出版信息

Probl Khig. 1993;18:124-31.

PMID:7845962
Abstract

Rapid and cheap test is developed on the basis of colorimetric tubes "Hygitest", produced in Bulgaria, which could substitute, in a number of cases, the more expensive chromatographic procedure. The method of gas extraction of the examined material is used in the test, and as measuring instrument are used colorimetric tubes "Hygitest" type "Vinylchloride-1-A", which are supplied with reinforced filter for humidity and with special scale. A specially constructed flask is used for thermal desorption. The test has reproducibility and sensitivity significant for performing screening and routine control on the raw materials for production of packings from polyvinylchloride for nutrition purposes. The method "Vinyl-test" is standardized for control on the free monomer content in the packings for nutrition purposes with branch normal of the Ministry of Health and the State firm "Polychim" OH 02 77051-84 (Change No 1 of 8.07.1991).

摘要

基于保加利亚生产的“Hygitest”比色管开发了一种快速且廉价的检测方法,在许多情况下,该方法可以替代更昂贵的色谱法。该检测使用被测物质的气体萃取方法,使用的测量仪器是“Hygitest”型“氯乙烯-1-A”比色管,这些比色管配有强化湿度过滤器和特殊刻度。使用一个特殊构造的烧瓶进行热解吸。该检测方法具有可重复性和灵敏度,对于对用于营养目的的聚氯乙烯包装生产原料进行筛选和常规控制具有重要意义。“乙烯基检测”方法已标准化,用于根据卫生部和国家公司“Polychim”的OH 02 77051-84(1991年7月8日第1号变更)的部门标准,对营养目的包装中的游离单体含量进行控制。

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1
[A rapid test for determining the content of residual monomer in polyvinyl chloride dust and granulate].[一种用于测定聚氯乙烯粉尘和颗粒中残留单体含量的快速检测方法]
Probl Khig. 1993;18:124-31.
2
Headspace sampling and gas-solid chromatographic determination and confirmation of greater than or equal to 1 ppb vinyl chloride residues in polyvinyl chloride food packaging.顶空进样和气相色谱法测定及确证聚氯乙烯食品包装中氯乙烯残留量≥1 ppb。
J Assoc Off Anal Chem. 1978 Jul;61(4):813-9.
3
[Migration of vinyl chloride monomer from polyvinylchloride materials and its regulation].
Gig Sanit. 1984 Jan(1):55-7.
4
Gas-liquid chromatographic determination of vinyl chloride in vinyl chloride polymers, food-simulating solvents, and other samples.气相色谱法测定氯乙烯聚合物、食品模拟溶剂及其他样品中的氯乙烯。
J Assoc Off Anal Chem. 1975 Nov;58(6):1214-20.
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[Method of determination of vinyl chloride in polyvinyl chloride material used for food packaging].
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Environmental carcinogens selected methods of analysis. Volume 2-Methods for the measurement of vinyl chloride in poly (vinyl chloride), air, water and foodstuffs.
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Interaction of vinyl chloride with poly(vinyl chloride) by inverse gas chromatography: effect of monomer concentration, plasticizer content and temperature.
Z Lebensm Unters Forsch. 1986 Aug;183(2):123-7. doi: 10.1007/BF01041929.
8
Repeatability and reproducibility of measurements of vinyl chloride concentrations in materials and articles made of polyvinyl chloride.
Food Cosmet Toxicol. 1980 Oct;18(5):527-35. doi: 10.1016/0015-6264(80)90169-8.
9
Determination of vinyl chloride monomer residue in poly(vinyl chloride) at the parts-per-billion level with an automatic purge-and-trap technique.采用自动吹扫捕集技术测定聚氯乙烯中十亿分之一级别的氯乙烯单体残留量。
J Chromatogr. 1987 Jun 12;395:281-9. doi: 10.1016/s0021-9673(01)94117-2.
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[Dust content of the working environment in work with polyvinyl chloride].[聚氯乙烯作业工作环境中的粉尘含量]
Gig Tr Prof Zabol. 1981 Dec(12):7-10.