Reddy M C
Department of Chemistry, G.P.R. Engineering College, Kurnool, A.P.
Indian J Biochem Biophys. 1994 Apr;31(2):131-5.
The Rayleigh ratio for young human and cataractous lenses, having spherical particles with constant diameter embedded in a medium with a different refractive index, has been calculated as a function of concentration (volume fraction) using the theory of the small-q behaviour of the static structure factor, S(q). It involves treating the long-range forces between particles in the gel in the random phase approximation, dividing the pairwise interaction potential into a reference part and a perturbed part based on WCA model, and applying the perturbation approach of WCA to lenses obeying van der Waals' potential as a perturbative attraction over the Percus-Yevick (PY) hard sphere model. The calculated Rayleigh ratios are found in excellent agreement with experimental values, thereby showing that the present model works well for young human and cataractous lenses.
对于年轻人类晶状体和白内障晶状体,其中球形颗粒直径恒定且嵌入在具有不同折射率的介质中,利用静态结构因子S(q)的小q行为理论,计算了瑞利比作为浓度(体积分数)的函数。这涉及在随机相位近似下处理凝胶中颗粒间的长程力,基于WCA模型将成对相互作用势分为参考部分和微扰部分,并将WCA的微扰方法应用于服从范德华势的晶状体,该势作为对Percus-Yevick(PY)硬球模型的微扰吸引。计算得到的瑞利比与实验值高度吻合,从而表明本模型适用于年轻人类晶状体和白内障晶状体。