The effect of ortho substitution on the mass spectral fragmentation of polychlorinated biphenyls.

Isomeric chlorinated biphenyls are observed to yield very similar mass spectra, rarely exhibiting a [M - Cl]+ fragment of any significant magnitude. However, those isomers containing three ortho chloro substituents display a relatively intense [M - Cl]+ fragment. A rationalization for this observation is put forth on the basis of the relative stabilities of both product and reactant.