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Stereoselective preparation of alkyl glycosides of 2-acetamido-2-deoxy-alpha-D-glucopyranose by nonclassical halide-ion catalysis and synthesis and NMR spectroscopy of alpha-D-Gal p-(1-->3)-alpha-D-Glc pNAc-OMe.

作者信息

Pozsgay V, Coxon B

机构信息

Laboratory of Developmental and Molecular Immunity, National Institute of Child Health and Human Development, National Institutes of Health, Bethesda, MD 20892, USA.

出版信息

Carbohydr Res. 1995 Nov 7;277(1):171-8. doi: 10.1016/0008-6215(95)00198-3.

DOI:10.1016/0008-6215(95)00198-3
PMID:8548787
Abstract
摘要

相似文献

1
Stereoselective preparation of alkyl glycosides of 2-acetamido-2-deoxy-alpha-D-glucopyranose by nonclassical halide-ion catalysis and synthesis and NMR spectroscopy of alpha-D-Gal p-(1-->3)-alpha-D-Glc pNAc-OMe.通过非经典卤离子催化立体选择性制备2-乙酰氨基-2-脱氧-α-D-吡喃葡萄糖的烷基糖苷以及α-D-半乳糖p-(1→3)-α-D-葡萄糖pNAc-OMe的合成与核磁共振光谱分析
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2
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All-aqueous, regiospecific transglycosylation synthesis of 3-O-alpha-L-fucopyranosyl-2-acetamido-2-deoxy-D-glucopyranose, a building block for the synthesis of branched oligosaccharides.3-O-α-L-呋喃岩藻糖基-2-乙酰氨基-2-脱氧-D-吡喃葡萄糖的全水相区域特异性转糖基化合成，一种用于合成支链寡糖的结构单元。
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Synthesis of disaccharide glycosyl donors suitable for introduction of the beta-D-Gal p-(1-->3)-alpha-and-beta-D-Gal pNAc groups.适用于引入β-D-半乳糖基-(1→3)-α-和β-D-半乳糖胺基的二糖糖基供体的合成。
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Protein conjugates of synthetic saccharides elicit higher levels of serum IgG lipopolysaccharide antibodies in mice than do those of the O-specific polysaccharide from Shigella dysenteriae type 1.与来自1型痢疾志贺氏菌的O特异性多糖的蛋白缀合物相比，合成糖类的蛋白缀合物在小鼠中引发更高水平的血清IgG脂多糖抗体。
Proc Natl Acad Sci U S A. 1999 Apr 27;96(9):5194-7. doi: 10.1073/pnas.96.9.5194.