Suppr超能文献

[饮用水中的铅、其浓度的测定以及世界卫生组织(WHO)新建议对公共和私人供水网络管理的影响]

[Lead in drinking water, determination of its concentration and effects of new recommendations of the World Health Organization (WHO) on public and private networks management].

作者信息

Vilagines R, Leroy P

机构信息

Centre de Recherche et de Contrôle des Eaux de la Ville de Paris (CRECEP), Paris.

出版信息

Bull Acad Natl Med. 1995 Oct;179(7):1393-408.

PMID:8556413
Abstract

In 1993, the World Health Organization (WHO) has given a guideline value of 10 microgram/l for lead in drinking water, a phased approach should lead to a temporary parametric value of 25 micrograms/l within 5 years the final concentration value of 10 micrograms/l being achieved after 15 years. So far the current European Community Directive 80/778 and the French decree 89/3 stipulate a Maximum Admissible Concentration (MAC) for lead of 50 micrograms/l. In a first step we studied the mechanisms of plumbosolvency in corrosive and scaling water. In the first case we have shown that simple oxidative corrosion of lead pipes forms a coating of lead carbonate and hydroxicarbonate on the inside wall of the pipe but "plumbosolvent" waters can dissolve those products, although at a lower level, resulting in a rather high lead concentration. In the case of scaling waters there is a co-precipitation of insoluble calcium carbonate but only on the microcathodics zones of the lead pipe. As this precipitate is poorly cohesive and does not cover the entire surface of the pipe its oxidative corrosion can proceed. In a second step we have shown the major importance of sampling for the determination of lead concentration in drinking water. We therefore compared random day time sampling, first draw and flushed samplings and composite proportional sampling. Only this last method gave a reasonably accurate idea of lead's amounts ingested by drinking water's consumers. The control of corrosion in lead-containing materials involves two successive steps: the reduction of lead concentration to 25 micrograms/l within five years and the compliance with the final 10 micrograms/l concentration 15 years later. The first step consists in water treatments such as pH increase, adjustment of alkalinity and addition of orthophospates. But available data suggest that it is unlikely that lead concentration could be reduced consistently to below 10 micrograms/l by avalable water treatment methods alone but it would enable to match the parametric 25 micrograms/l value in the great majority of cases. Therefore, to unable compliance with the 10 micrograms/l parametric value, it will be necessary to replace all the internal plumbing and supply lead pipes (70,000 buildings for Paris only). Data for materials able to replace lead such as plastic pipes are not yet complete and an currently under investigations. Although the United States Environmental Protection Agency have suggested in its 1988 report on air quality criteria for lead report (EPA 600/8-33-028 aF-dF) that each 1 microgram/l of lead in water can lead to an increase of blood lead levels of approximately 0.2 micrograms/l for a child, the data are still uncertain. The considerable cost of these works (143 billion of french francs for France and 347 billions of french francs for Europe), unrelated to any important Public Health problems, arises an ethical problem which has to be considered in view of many others letal illnesses such as heart and circulatory diseases, cancer and AIDS.

摘要

1993年,世界卫生组织(WHO)给出了饮用水中铅的指导值为10微克/升,分阶段实施应在5年内达到临时参数值25微克/升,15年后实现最终浓度值10微克/升。到目前为止,现行的欧洲共同体指令80/778和法国法令89/3规定铅的最大允许浓度(MAC)为50微克/升。第一步,我们研究了腐蚀性水和结垢水中铅溶解的机制。在第一种情况下,我们发现铅管的简单氧化腐蚀会在管壁内侧形成碳酸铅和碱式碳酸铅涂层,但“铅溶剂性”水可以溶解这些产物,尽管溶解程度较低,导致铅浓度相当高。在结垢水的情况下,不溶性碳酸钙会共沉淀,但仅在铅管的微阴极区域。由于这种沉淀物粘结性差,不能覆盖管道的整个表面,其氧化腐蚀仍会继续。第二步,我们证明了饮用水中铅浓度测定时采样的重要性。因此,我们比较了随机日间采样、首次抽取和冲洗采样以及复合比例采样。只有最后这种方法能合理准确地反映饮用水消费者摄入的铅量。含铅材料的腐蚀控制包括两个连续步骤:在5年内将铅浓度降至25微克/升,并在15年后符合最终的10微克/升浓度。第一步包括水处理,如提高pH值、调节碱度和添加正磷酸盐。但现有数据表明,仅通过现有的水处理方法不太可能将铅浓度持续降至10微克/升以下,但在大多数情况下能够达到参数值25微克/升。因此,为了符合10微克/升的参数值,有必要更换所有内部管道和供水铅管(仅巴黎就有70000栋建筑)。能够替代铅的材料(如塑料管)的数据尚不完整,目前正在进行调查。尽管美国环境保护局在其1988年关于铅的空气质量标准报告(EPA 600/8 - 33 - 028 aF - dF)中指出,水中每1微克/升的铅会使儿童血铅水平大约增加0.2微克/升,但数据仍不确定。这些工程的成本巨大(法国为1430亿法国法郎,欧洲为3470亿法国法郎),且与任何重大公共卫生问题无关,这引发了一个伦理问题,鉴于许多其他致命疾病,如心脏病、循环系统疾病、癌症和艾滋病,必须予以考虑。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验