Greenwald S M, Hancock A J, Sable H Z, D'Esposito L, Koenig J L
Chem Phys Lipids. 1977 Mar;18(2):154-69. doi: 10.1016/0009-3084(77)90003-2.
The polymorphic behavior of three series of tris-homoacyl (C14:0, C16:0 and C18:0) cyclopentane-1,2,3-triol analogs of the natural saturated triglycerides has been studied using differential thermal analysis, Fourier transform infrared spectroscopy, and X-ray diffraction. It was found that the triglyceride analogs derived from the 1,2,3/0 and 1,2/3 cyclopentanetriols exhibit different polymorphic behavior than that of the natural triglycerides. The analogs derived from 1,3/2 cyclopentanetriol, however, were found to parallel the polymorphic behavior of the natural triglycerides quite closely. This polymorphic behavior is discussed in terms of the different configurations which the chains assume in each of the triglyceride analogs.
利用差示热分析、傅里叶变换红外光谱和X射线衍射研究了天然饱和甘油三酯的三个系列的三同酰基（C14:0、C16:0和C18:0）环戊烷-1,2,3-三醇类似物的多晶型行为。结果发现，源自1,2,3/0和1,2/3环戊三醇的甘油三酯类似物表现出与天然甘油三酯不同的多晶型行为。然而，发现源自1,3/2环戊三醇的类似物与天然甘油三酯的多晶型行为非常相似。根据每个甘油三酯类似物中链所呈现的不同构型对这种多晶型行为进行了讨论。
