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Double rotation and magic-angle spinning nuclear magnetic resonance study of 27Al: reexamination of the aluminium borate 9Al2O3.2B2O3.

作者信息

Massiot D, Müller D, Hübert T, Schneider M, Kentgens A P, Coté B, Coutures J P, Gessner W

机构信息

Centre de Recherche sur la Physique des Hautes Températures, Orléans, France.

出版信息

Solid State Nucl Magn Reson. 1995 Nov;5(2):175-80. doi: 10.1016/0926-2040(95)00021-h.

DOI:10.1016/0926-2040(95)00021-h
PMID:8748655
Abstract

27Al nuclear magnetic resonance spectra of polycrystalline aluminium borate 9Al2O3.2B2O3 have been measured in double rotation at 11.7 and 7.0 T and high-speed magic-angle spinning at 7.0, 9.4, 11.7, 14.1 and 17.6 T. Spinning sidebands from the satellite transitions were observed at 7.0 and 14.1 T. Each of the four structural aluminium sites [Al(IV), Al(V)(1), Al(V)(2) and Al(VI)] are observed, characterised and assigned in the spectra. The obtained parameter set gives a fully consistent interpretation in agreement with the crystal structure of the compound.

摘要

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