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[法医毒理学中通过光谱方法鉴定有机物质。I. 红外光谱法]

[Identification of organic substances by means of spectral methods in forensic toxicology. I. Infrared spectroscopy].

作者信息

Smysl B

出版信息

Soud Lek. 1976 Feb;21(1):7-13.

PMID:8843
Abstract

In the introduction the author gives an outline of the principles of infrared spectroscopy and possibilities of its use for the identification of organic substances. On examples from practice he demonstrates the use of infrared spectroscopy in forensic toxicology. He desribes methods for the isolation of substances from biological material and methods of their purification. The applied methods are used for common toxicological analyses. Attention is drawn to the possibility of comprehensive identification of the structure or a comound based on an analysis of the infrared spetrum and analysis of a mixture of two substances is is described. Infrared spectroscopy is a very suitable method for the unequivocal identification even of very small amounts of substances obtained from material (biological and corpora delicti) in intoxications with organic substances, such a as drugs, pesticides, etc.

摘要

在引言部分,作者概述了红外光谱法的原理及其用于鉴定有机物质的可能性。通过实际案例,他展示了红外光谱法在法医毒理学中的应用。他描述了从生物材料中分离物质的方法及其纯化方法。这些应用方法用于常规毒理学分析。文中提到了基于红外光谱分析对化合物结构进行全面鉴定的可能性,并描述了两种物质混合物的分析方法。红外光谱法是一种非常适合明确鉴定从有机物质中毒(如药物、农药等)的材料(生物和犯罪现场物证)中获取的极少量物质的方法。

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