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酶促反应中电流对混沌的控制

Chaos control by electric current in an enzymatic reaction.

作者信息

Lekebusch A, Förster A, Schneider F W

机构信息

Institute of Physical Chemistry, University of Würzburg, Germany.

出版信息

Int J Neural Syst. 1996 Sep;7(4):393-7. doi: 10.1142/s0129065796000361.

Abstract

We apply the continuous delayed feedback method of Pyragas to control chaos in the enzymatic Peroxidase-Oxidase (PO) reaction, using the electric current as the control parameter. At each data point in the time series, a time delayed feedback function applies a small amplitude perturbation to inert platinum electrodes, which causes redox processes on the surface of the electrodes. These perturbations are calculated as the difference between the previous (time delayed) signal and the actual signal. Unstable periodic P1, 1(1), and 1(2) orbits (UPOs) were stabilized in the CSTR (continuous stirred tank reactor) experiments. The stabilization is demonstrated by at least three conditions: A minimum in the experimental dispersion function, the equality of the delay time with the period of the stabilized attractor and the embedment of the stabilized periodic attractor in the chaotic attractor.

摘要

我们应用皮拉加斯的连续延迟反馈方法,以电流作为控制参数,来控制酶促过氧化物酶-氧化酶(PO)反应中的混沌现象。在时间序列的每个数据点,一个时间延迟反馈函数会对惰性铂电极施加小幅度扰动,这会引发电极表面的氧化还原过程。这些扰动是以前一个(时间延迟)信号与实际信号之间的差值来计算的。在连续搅拌釜式反应器(CSTR)实验中,不稳定的周期P1、1(1)和1(2)轨道(UPOs)得以稳定。这种稳定至少通过三个条件得以证明:实验色散函数中的最小值、延迟时间与稳定吸引子周期的相等以及稳定周期吸引子嵌入混沌吸引子之中。

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