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N2 Broadening in the 13C16O 2-0 Band around 4167 cm-1.

作者信息

Voigt S, Dreher S, Orphal J, Burrows JP

机构信息

Institute of Environmental Physics, University of Bremen, Bremen, D-28334, Germany

出版信息

J Mol Spectrosc. 1996 Dec;180(2):359-64. doi: 10.1006/jmsp.1996.0259.

Abstract

N2 broadening coefficients have been measured for 65 lines of the 13C16O 2-0 band using a Fourier transform spectrometer. These lines are located in the spectral range 4011-4252 cm-1. The spectra were recorded with 99% isotopically pure 13CO in a White-type cell at a resolution of 0.005 cm-1. Voigt profiles convolved with the FTS apparatus function were fitted to the experimental lineshapes using a nonlinear least-squares fit technique. From the fits the Lorentzian HWHM was determined as function of N2 pressure. Pressure broadening coefficients for m between -33 and +34 were obtained with uncertainties of 5.8%. The results are compared to earlier published N2 broadening coefficients and our measurements in the 2-0 band of 12C16O. To our knowledge this is the first investigation of 13CO pressure broadening.

摘要

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