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Electrophoretic Mobility of a Polyelectrolyte-Adsorbed Particle: Effect of Segment Density Distribution.

作者信息

Ohshima H

机构信息

Faculty of Pharmaceutical Sciences and Institute of Colloid and Interface Science, Science University of Tokyo, 12 Ichigaya Funagawara-machi, Shinjuku-ku, Tokyo , 162, Japan

出版信息

J Colloid Interface Sci. 1997 Jan 1;185(1):269-73. doi: 10.1006/jcis.1996.4601.

DOI:10.1006/jcis.1996.4601
PMID:9056349
Abstract

Varoqui's theory [Nouv. J. Chim. 6, 187 (1982)] for the electrophoretic mobility of a charged colloidal particle adsorbed by neutral polymers with an exponential distribution of the polymer segments is extended to the case where adsorbed polymers are charged. An analytic mobility expression is derived on the basis of the linearized Poisson-Boltzmann equation. Comparison is made with the case of particles coated with a polyelectrolyte layer of fixed thickness with uniform segment distribution.

摘要

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