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CD3OH中C-O伸缩带的研究:远红外激光谱线的归属

Investigation of C-O Stretching Band of CD3OH: Assignments of Far-Infrared Laser Lines.

作者信息

Moraes JCS

机构信息

Departamento de Fisica e Quimica, FEIS-UNESP, Ilha Solteira, SP, 15.385-000, Brazil

出版信息

J Mol Spectrosc. 1997 Oct;185(2):325-9. doi: 10.1006/jmsp.1997.7403.

DOI:10.1006/jmsp.1997.7403
PMID:9398569
Abstract

We have investigated the high-resolution Fourier transform spectrum of the C-O stretching fundamental band of CD3OH in order to assign far-infrared (FIR) laser transitions. The absorption spectrum was analyzed by means of the "Ritz" program, which calculates the energy level values directly from the Rydberg-Ritz combination principle. We have also used the "LaseRitz" program to facilitate the assignment of the FIR laser lines. As a consequence we could determine 12 new assignments, confirming 4 previously proposed ones and predicting new FIR laser emissions. Copyright 1997 Academic Press. Copyright 1997Academic Press

摘要

为了确定远红外(FIR)激光跃迁,我们研究了CD3OH中C - O伸缩基频带的高分辨率傅里叶变换光谱。吸收光谱通过“Ritz”程序进行分析,该程序直接根据里德伯 - 里兹组合原理计算能级值。我们还使用了“LaseRitz”程序来辅助FIR激光谱线的确定。结果我们确定了12个新的谱线归属,证实了4个先前提出的归属,并预测了新的FIR激光发射。版权所有1997年学术出版社。版权所有1997年学术出版社

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