Bu X, Feng P, Stucky GD
X. Bu and P. Feng are in the Department of Chemistry and G. D. Stucky is in the Department of Chemistry and Department of Materials, University of California, Santa Barbara, CA 93106, USA.
Science. 1997 Dec 19;278(5346):2080-5. doi: 10.1126/science.278.5346.2080.
Zeolite type structures with large cages interconnected by multidimensional 12-ring (rings of 12 tetrahedrally coordinated atoms) channels have been synthesized; more than a dozen large-pore materials were created in three different topologies with aluminum (or gallium), cobalt (or manganese, magnesium, or zinc), and phosphorus at the tetrahedral coordination sites. Tetragonal UCSB-8 has an unusually large cage built from 64 tetrahedral atoms and connected by an orthogonal channel system with 12-ring apertures in two dimensions and 8-ring apertures in the third. Rhombohedral UCSB-10 and hexagonal UCSB-6 are structurally related to faujasite and its hexagonal polymorph, respectively, and have large cages connected by 12-ring channels in all three dimensions.
已合成出具有由多维12元环（12个四面体配位原子环）通道相互连接的大笼子的沸石型结构；在三种不同拓扑结构中制备了十几种大孔材料，其四面体配位位点含有铝（或镓）、钴（或锰、镁或锌）和磷。四方晶系的UCSB - 8具有由64个四面体原子构成的异常大的笼子，并通过一个正交通道系统相连，该通道系统在二维有12元环孔口，在三维有8元环孔口。菱面体晶系的UCSB - 10和六方晶系的UCSB - 6分别在结构上与八面沸石及其六方多晶型物相关，并且在所有三个维度上都有由12元环通道连接的大笼子。
