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通过仪器中子活化分析研究巴西东北部种植的卡廷加木与土壤之间稀土元素、铝和钪的分配情况。

Rare earth element, Al, and Sc partition between soil and Caatinger wood grown in north-east Brazil by instrumental neutron activation analysis.

作者信息

Nakanishi T M, Takahashi J, Yagi H

机构信息

Graduate School of Agricultural and Life Sciences, The University of Tokyo, Japan.

出版信息

Biol Trace Elem Res. 1997 Dec;60(3):163-74. doi: 10.1007/BF02784437.

Abstract

Seven representative wood species constituting Caatinger forest in north-east Brazil were chosen to analyze La, Ce, Sm, Eu, Yb, Sc, and Al by instrumental neutron activation analysis (INAA). Soil profiles were prepared where the trees were downed. Then soil and root samples from each horizontal soil layer, as well as the upper part of the wood, ground-level bark, and the bark at 1 m above were collected. In woods, the rare earth element (REE) was found to be mainly accumulated in root, which concentration was in the same order as that of soil. In all samples, concentration of La and Ce were found to be about ten times higher than those of the other REEs. The REE accumulation became higher, in both root and soil, in the order of La, Ce, and Sm. The partition rate of La and Eu was higher from soil to root, whereas Ce tended to be concentrated from root to bark. In the case of bark, there was no tendency of specific REE accumulating from ground level to the upper part. The correlation of La concentration to the other REE was higher in root than that of corresponding soil. Roots also showed higher correlation of REE to Al and Sc than that of soil or bark.

摘要

选取了构成巴西东北部卡廷加森林的七种代表性木材物种,通过仪器中子活化分析(INAA)来分析镧(La)、铈(Ce)、钐(Sm)、铕(Eu)、镱(Yb)、钪(Sc)和铝(Al)。在树木倒下的地方制备土壤剖面。然后从每个水平土壤层以及木材上部、地面树皮和上方1米处的树皮收集土壤和根系样本。在树林中,发现稀土元素(REE)主要积累在根部,其浓度与土壤中的浓度顺序相同。在所有样本中,发现镧和铈的浓度比其他稀土元素高出约十倍。稀土元素在根和土壤中的积累按照镧、铈和钐的顺序变得更高。镧和铕从土壤到根的分配率较高,而铈则倾向于从根向树皮集中。就树皮而言,从地面到上部没有特定稀土元素积累的趋势。根中镧浓度与其他稀土元素的相关性高于相应土壤中的相关性。根中稀土元素与铝和钪的相关性也高于土壤或树皮中的相关性。

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