某些芳烷基胺的圆二色性研究
Circular dichroism studies of some aralkylamines.
作者信息
Ghislandi V, La Manna A, Vercesi D
出版信息
Farmaco Sci. 1976 Aug;31(8):561-71.
PMID:955058
Abstract
Circular dichroism curves are reported for a number of aralkylamines having a general formula R--CH(NH2)--R' (in which R and R' are alkyl-, aryl- or aralkyl-groups) and for 1-aminobenzocyclobutene, 1-aminoindane, 1-amino-1,2,3,4-tetrahydronaphthalene and 2-amino-1,2,3,4-tetrahydronaphthalene. The Cotton effects due to aromatic chromophore 1Lb and 1La absorption bands are discussed and simple correlations between absolute configuration and the signs of Cotton effects are deduced.
摘要
报道了一系列通式为R-CH(NH₂)-R'（其中R和R'为烷基、芳基或芳烷基）的芳烷基胺以及1-氨基苯并环丁烯、1-氨基茚满、1-氨基-1,2,3,4-四氢萘和2-氨基-1,2,3,4-四氢萘的圆二色性曲线。讨论了由于芳香发色团1Lb和1La吸收带引起的科顿效应，并推导了绝对构型与科顿效应符号之间的简单相关性。
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