Hopfield J J
Biophys J. 1976 Oct;16(10):1239-40. doi: 10.1016/S0006-3495(76)85769-4.
The tunneling transfer of electrons between two sites, appropriate to biological intermolecular electron transfer, contains physical considerations which are not important in the tunneling transfer between two metals. Analyses (such as the recent one by Hales) based on the well-known formula for the latter but applied to the former case are quantitatively and qualitatively misleading.
两个位点之间电子的隧穿转移适用于生物分子间的电子转移,其中包含一些物理因素,这些因素在两种金属之间的隧穿转移中并不重要。基于适用于后者的著名公式但应用于前一种情况的分析(例如最近黑尔斯所做的分析)在定量和定性方面都具有误导性。