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常压下的氨合成。

Ammonia synthesis at atmospheric pressure.

作者信息

Marnellos G, Stoukides M

机构信息

Chemical Engineering Department and Chemical Process Engineering Research Institute, Aristotle University of Thessaloniki, Thessaloniki 54006, Greece.

出版信息

Science. 1998 Oct 2;282(5386):98-100. doi: 10.1126/science.282.5386.98.

Abstract

Ammonia was synthesized from its elements at atmospheric pressure in a solid state proton (H+)-conducting cell-reactor. Hydrogen was flowing over the anode and was converted into protons that were transported through the solid electrolyte and reached the cathode (palladium) over which nitrogen was passing. At 570 degreesC and atmospheric pressure, greater than 78 percent of the electrochemically supplied hydrogen was converted into ammonia. The thermodynamic requirement for a high-pressure process is eliminated.

摘要

在常压下,通过固态质子(H⁺)传导电池反应器由其元素合成了氨。氢气在阳极上流动并转化为质子,这些质子通过固体电解质传输并到达阴极(钯),氮气在阴极上通过。在570℃和常压下,超过78%的电化学供应的氢气转化为氨。消除了高压过程的热力学要求。

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