New Carbon-Silica Composite Adsorbents from Elutrilithe.

Carbon-silica composite adsorbents with high surface area and pore volume were prepared from natural elutrilithe. The elutrilithe was chemically activated with K2CO3 at 1123 K and then dissolved in water. The textural and adsorptive properties of the composite adsorbents can be adjusted by varying the pH and concentration of the sol mixture and the gel aging temperature. Composite adsorbents prepared at low concentration have high adsorption capacities for both water (43.4%) and cyclohexane (32.0%), exceeding those of ordinary commercial silica gel and active carbon. The adsorbents prepared at high concentration are more hydrophobic in nature, with adsorption capacities for water and cyclohexane of 18.5 and 41.5%, respectively. The composite adsorbents are resistant to repetitive adsorption and regeneration cycles. Copyright 1998 Academic Press.