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通过脉冲场梯度核磁共振研究径向压缩珠状填料中的空间分辨传输特性。

Spatially resolved transport properties in radially compressed bead packings studied by PFG NMR.

作者信息

Van Dusschoten D, Tallarek U, Scheenen T, Neue U D, Van As H

机构信息

Wageningen Nuclear Magnetic Resonance Centre (WNMRC), Wageningen Agricultural University, The Netherlands.

出版信息

Magn Reson Imaging. 1998 Jun-Jul;16(5-6):703-6. doi: 10.1016/s0730-725x(98)00018-6.

DOI:10.1016/s0730-725x(98)00018-6
PMID:9803945
Abstract

Pulsed field gradient (PFG) multi-echo (ME) and turbo spin-echo (TSE) imaging is used to study dispersive flow in radially compressed chromatographic columns packed with porous silica beads. By using the pulsed field gradient turbo spin-echo sequence spatially resolved displacement imaging can be accelerated by a factor of 16. The positive effect of homogeneous radial packing on flow velocity and dispersion is demonstrated. Small heterogeneities of only a few percent are shown to cause changes of the dispersion coefficient of up to 50%.

摘要

脉冲场梯度(PFG)多回波(ME)和快速自旋回波(TSE)成像用于研究填充有多孔硅胶珠的径向压缩色谱柱中的分散流。通过使用脉冲场梯度快速自旋回波序列,空间分辨位移成像的速度可加快16倍。证明了均匀径向填充对流速和分散的积极影响。仅百分之几的小不均匀性就会导致分散系数变化高达50%。

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