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二氧化碳碳-12氧-17同位素物种激光带中的谱线位置和绝对强度

Line Positions and Absolute Intensities in the Laser Bands of Carbon-12 Oxygen-17 Isotopic Species of Carbon Dioxide.

作者信息

Claveau C, Teffo J, Hurtmans D, Valentin A, Gamache RR

机构信息

Laboratoire de Physique Moléculaire et Applications, CNRS, Boite 76, Université Pierre et Marie Curie, 4 Place Jussieu, Paris Cedex 05, 75252, France

出版信息

J Mol Spectrosc. 1999 Jan;193(1):15-32. doi: 10.1006/jmsp.1998.7704.

Abstract

Infrared spectra of a carbon dioxide sample enriched with oxygen-17 have been recorded with a resolution of about 0.0025 cm-1 in the region of the laser bands near 10 and 9 µm, using the long path difference Fourier Transform Spectrometer of the LPMA in Paris. The two laser bands of the 16O12C17O and 17O12C18O species have been analyzed for the first time. Line intensities for several isotopic species have been measured in this region and the rotationless transition dipole moments and Herman-Wallis coefficients of the corresponding bands have been reported. In particular intensities, alternation in the spectra of 17O12C17O has been analyzed. Copyright 1999 Academic Press.

摘要

利用巴黎LPMA的长程差傅里叶变换光谱仪,在10和9微米附近的激光波段区域,以约0.0025厘米⁻¹的分辨率记录了富含氧-17的二氧化碳样品的红外光谱。首次分析了¹⁶O¹²C¹⁷O和¹⁷O¹²C¹⁸O物种的两个激光波段。在该区域测量了几种同位素物种的谱线强度,并报告了相应波段的无转动跃迁偶极矩和赫尔曼-沃利斯系数。特别对¹⁷O¹²C¹⁷O光谱中的强度交替进行了分析。版权所有1999年学术出版社。

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