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消费级滑石粉和爽身粉:矿物与化学特性

Consumer talcums and powders: mineral and chemical characterization.

作者信息

Rohl A N, Langer A M, Selikoff I J, Tordini A, Klimentidis R, Bowes D R, Skinner D L

出版信息

J Toxicol Environ Health. 1976 Nov;2(2):255-84. doi: 10.1080/15287397609529432.

Abstract

Representative consumer talcums and powders, including 20 body powders, baby powders, facial talcums, and also one pharmaceutical talc, were analyzed to determine their mineralogical and chemical composition. Where known, all were formulated prior to 1973. Of the 20 products 10 contained detectable amounts of tremolite and anthophyllite, principally asbestiform, while some also contained fragmented forms of these minerals. The amounts ranged from tenths of a percent to over 14% by weight; two contained detectable amounts of chrysotile asbestos fiber. Eight contained quartz, seven ranging from 2 to 5%, with one as high as 35%. The analyses showed that the consumer products examined were rarely the pure mineral talc, but rather were mixtures of various minerals; some samples consisted of three to five minerals, only one of which was talc. Other common mineral phases included chlorite, platy serpentine, pyrophyllitem mica, and carbonate minerals. Kaolin additive was identified in two products. The single pharmaceutical talc examined contained only a trace amount of quartz. The chemical composition of these products, including both major oxide and trace element content, correlated with their mineral components. Four samples contained substantial concentrations of nickel, cobalt, and chromium, suggesting latice substitution or the presence of trace mineral phases. Geological provenance of the talcs may be ascertained on the basis of chemistry. Possible adverse health effects from intermittent use of these products, especially those that contain asbestiform and fragmented anthophyllite and tremolite, chrysotile, quartz, and trace metals, are presently unknown and warrnat evaluation.

摘要

对包括20种爽身粉、婴儿爽身粉、面部滑石粉以及一种药用滑石粉在内的代表性消费用滑石粉和粉末进行了分析,以确定其矿物学和化学组成。已知所有产品均在1973年之前配制。在这20种产品中,有10种含有可检测量的透闪石和直闪石,主要为石棉状,有些还含有这些矿物的碎片形式。含量范围从十分之几重量百分比到超过14%;有两种含有可检测量的温石棉纤维。8种含有石英,7种含量在2%至5%之间,有一种高达35%。分析表明,所检测的消费产品很少是纯矿物滑石,而是各种矿物的混合物;一些样品由三到五种矿物组成,其中只有一种是滑石。其他常见的矿物相包括绿泥石、片状蛇纹石、叶蜡石、云母和碳酸盐矿物。在两种产品中鉴定出高岭土添加剂。所检测的单一药用滑石粉仅含有痕量的石英。这些产品的化学成分,包括主要氧化物和微量元素含量,与其矿物成分相关。四个样品含有大量的镍、钴和铬,表明存在晶格替代或微量矿物相。滑石的地质来源可以根据化学性质确定。目前尚不清楚间歇性使用这些产品,尤其是那些含有石棉状和碎片状直闪石、透闪石、温石棉、石英和痕量金属的产品可能对健康产生的不良影响,需要进行评估。

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