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乙酸γ辐照过程中生物相关羧酸的形成。

Formation of biologically relevant carboxylic acids during the gamma irradiation of acetic acid.

作者信息

Negron-Mendoza A, Ponnamperuma C

出版信息

Orig Life. 1976 Aug;7(3):191-6. doi: 10.1007/BF00926937.

DOI:10.1007/BF00926937
PMID:1012709
Abstract

Irradiation of aqueous solutions of acetic acid with gamma rays produced several carboxylic acids in small yield. Their identification was based on the technique of gas chromatography combined with mass spectrometry. Some of these acids are Krebs Cycle intermediates. Their simultaneous formation in experiments simulating the primitive conditions on the earth suggests that metabolic pathways may have their origin in prebiotic chemical processes.

摘要

用伽马射线辐照乙酸水溶液会少量生成几种羧酸。它们的鉴定基于气相色谱与质谱联用技术。其中一些酸是三羧酸循环的中间产物。它们在模拟地球原始条件的实验中同时形成,这表明代谢途径可能起源于益生元化学过程。

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Gamma-irradiation of malic acid in aqueous solutions.水溶液中苹果酸的γ射线辐照

本文引用的文献

1
Organic compound synthesis on the primitive earth.原始地球上的有机化合物合成。
Science. 1959 Jul 31;130(3370):245-51. doi: 10.1126/science.130.3370.245.
2
A possible prebiotic synthesis of monocarboxylic acids.一元羧酸可能的益生元合成。
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The radiolysis of aqueous acetonitrile: compounds of interest to chemical evolution studies.
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Formation of amino acids from reactor-irradiated ammonium acetate.由反应堆辐照的醋酸铵生成氨基酸。
Orig Life. 1982 Dec;12(4):339-45. doi: 10.1007/BF00927065.
6
Chemical evolution of the citric acid cycle: sunlight photolysis of alpha-ketoglutaric acid.
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