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1
Chemistry and toxicity of flame retardants for plastics.塑料用阻燃剂的化学性质与毒性
Environ Health Perspect. 1976 Oct;17:55-63. doi: 10.1289/ehp.761755.
2
Public health implications of components of plastics manufacture. Flame retardants.塑料制造成分对公共卫生的影响。阻燃剂。
Environ Health Perspect. 1975 Jun;11:59-69. doi: 10.1289/ehp.751159.
3
Further toxicologic studies with commercial and candidate flame retardant chemicals. Part II.商用及候选阻燃化学品的进一步毒理学研究。第二部分。
Bull Environ Contam Toxicol. 1977 Jun;17(6):720-6. doi: 10.1007/BF01685960.
4
Playing with fire: the global threat presented by brominated flame retardants justifies urgent substitution.玩火自焚:溴化阻燃剂带来的全球威胁表明迫切需要进行替代。
Environ Int. 2003 Sep;29(6):725-34. doi: 10.1016/S0160-4120(03)00115-6.
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Toxicity of new generation flame retardants to Daphnia magna.新一代阻燃剂对大型溞的毒性。
Sci Total Environ. 2013 Oct 1;463-464:1042-8. doi: 10.1016/j.scitotenv.2013.06.110. Epub 2013 Jul 23.
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Neurotoxicity and risk assessment of brominated and alternative flame retardants.溴化阻燃剂及替代阻燃剂的神经毒性与风险评估
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Advanced morphological - behavioral test platform reveals neurodevelopmental defects in embryonic zebrafish exposed to comprehensive suite of halogenated and organophosphate flame retardants.先进的形态学-行为测试平台揭示了暴露于一系列卤代和有机磷酸酯阻燃剂中的斑马鱼胚胎的神经发育缺陷。
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Degradation of brominated polymeric flame retardants and effects of generated decomposition products.溴化高分子阻燃剂的降解及生成分解产物的影响。
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A new mutagenic and genotoxic response of the flame retardant tris(2,3-dibromopropyl)phosphate. Activation by singlet oxygen.阻燃剂磷酸三(2,3-二溴丙基)酯的一种新的诱变和遗传毒性反应。单线态氧的激活作用。
Mutat Res. 1980 Mar;77(3):209-14. doi: 10.1016/0165-1218(80)90052-x.

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A Detailed Review Study on Potential Effects of Microplastics and Additives of Concern on Human Health.微塑料及其关注添加剂对人类健康潜在影响的详细综述研究。
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8
Degradation of diphenylether by Pseudomonas cepacia Et4: enzymatic release of phenol from 2,3-dihydroxydiphenylether.洋葱伯克霍尔德菌Et4对二苯醚的降解:从2,3 - 二羟基二苯醚中酶促释放苯酚
Arch Microbiol. 1993;159(4):323-9. doi: 10.1007/BF00290914.

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1
Toxic and health effects of plastics and resins.塑料和树脂的毒性及健康影响
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Toxicology of plastics and rubber: plastomers and monomers.塑料和橡胶的毒理学:塑性体和单体
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3
Toxicity of 2-ethylhexyl diphenyl phosphate. IV. Skin sensitization studies of santicizer 141.磷酸二(2-乙基己基)酯的毒性。IV. 增塑剂141的皮肤致敏研究。
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Preliminary studies on the fate of inhaled vinyl chloride monomer (VCM) in rats.大鼠吸入氯乙烯单体(VCM)归宿的初步研究。
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塑料用阻燃剂的化学性质与毒性

Chemistry and toxicity of flame retardants for plastics.

作者信息

Liepins R, Pearce E M

出版信息

Environ Health Perspect. 1976 Oct;17:55-63. doi: 10.1289/ehp.761755.

DOI:10.1289/ehp.761755
PMID:1026419
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1475265/
Abstract

An overview of commercially used flame retardants is give. The most used flame retardants are illustrated and the seven major markets, which use 96% of all flame-retarded polymers, are described. Annual flame retardant growth rate for each major market is also projected. Toxicity data are reviewed on only those compositions that are considered commercially significant today. This includes 18 compounds or families of compounds and four inherently flame-retarded polymers. Toxicological studies of flame retardants for most synthetic materials are of recent origin and only a few of the compounds have been evaluated in any great detail. Considerable toxicological problems may exist in the manufacturing of some flame retardants, their by-products, and possible decomposition products.

摘要

本文给出了商用阻燃剂的概述。阐述了最常用的阻燃剂,并描述了使用了96%的所有阻燃聚合物的七个主要市场。还预测了每个主要市场的阻燃剂年增长率。仅对那些在当今被认为具有商业重要性的组合物进行了毒性数据审查。这包括18种化合物或化合物家族以及四种本质阻燃聚合物。大多数合成材料的阻燃剂的毒理学研究是最近才开始的,只有少数化合物得到了详细评估。在一些阻燃剂及其副产品和可能的分解产物的制造过程中可能存在相当大的毒理学问题。