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碳质微陨石与生命起源

Carbonaceous micrometeorites and the origin of life.

作者信息

Maurette M

机构信息

C.S.N.S.M., Batiment 104, 91405, Orsay-Campus, France.

出版信息

Orig Life Evol Biosph. 1998 Oct;28(4-6):385-412. doi: 10.1023/a:1006589819844.

Abstract

Giant micrometeorites (sizes ranging from approximately 50 to 500 micrometers), such as those that were first recovered from clean pre-industrial Antarctic ices in December 1987, represent by far the dominant source of extraterrestrial carbonaceous material accreted by the Earth's surface, about 50,000 times the amount delivered by meteorites (sizes > or = a few cm). They correspond to large interplanetary dust particles that survived unexpectedly well their hypervelocity impact with the Earth's atmosphere, contrary to predictions of theoretical models of such impacts. They are related to relatively rare groups of carbonaceous chondrites (approximately 2% of the meteorite falls) and not to the most abundant meteorites (oridinary chondrites and differentiated micrometeorites). About 80% of them appear to be highly unequilibrated fine-grained assemblages of mineral grains, where an abundant carbonaceous component is closely associated on a scale of < or = 0.1 micron to both hydrous and anhydrous minerals, including potential catalysts. These observations suggest that micrometeorites could have functioned as individual microscopic chemical reactors to contribute to the synthesis of prebiotic molecules on the early Earth, about 4 billion years ago. The recent identification of some of their complex organics (amino acids and polycyclic aromatic hydrocarbons), and the observation that they behave as very efficient 'cosmochromatographs', further support this 'early carbonaceous micrometeorite' scenario. Future prospects include identifying the host phases (probably ferrihydrite) of their complex organics, evaluating their catalytic activity, and assessing whether synergetic interactions between micrometeorites and favorable zones of the early Earth (such as submarine hydrothermal vents) accelerated and/or modified such synthesis.

摘要

巨型微陨石(尺寸范围约为50至500微米),比如那些于1987年12月首次从工业化前洁净的南极冰层中发现的微陨石,是迄今为止地球表面所吸积的外星含碳物质的主要来源,其数量是陨石(尺寸大于或等于几厘米)所带来数量的约50000倍。它们对应着大型行星际尘埃颗粒,这些颗粒在与地球大气的超高速撞击中意外地保存得很好,这与此类撞击的理论模型预测相反。它们与相对罕见的碳质球粒陨石群(约占陨石坠落数量的2%)有关,而与最常见的陨石(普通球粒陨石和分异微陨石)无关。其中约80%似乎是矿物颗粒的高度不平衡细粒集合体,其中丰富的含碳成分在小于或等于0.1微米的尺度上与含水和无水矿物紧密相连,包括潜在的催化剂。这些观察结果表明,微陨石可能曾作为单个微观化学反应器,在约40亿年前对早期地球上益生元分子的合成起到了促进作用。最近对它们一些复杂有机物(氨基酸和多环芳烃)的鉴定,以及它们表现得像非常高效的“宇宙色谱仪”这一观察结果,进一步支持了这种“早期含碳微陨石”的设想。未来的前景包括确定其复杂有机物的宿主相(可能是水铁矿)、评估它们的催化活性,以及评估微陨石与早期地球的有利区域(如海底热液喷口)之间的协同相互作用是否加速和/或改变了这种合成。

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