Kohen A, Klinman J P
Departments of Chemistry and Molecular and Cell Biology, University of California at Berkeley, Berkeley, CA 94720, USA.
Chem Biol. 1999 Jul;6(7):R191-8. doi: 10.1016/s1074-5521(99)80058-1.
The mechanistic details of hydrogen transfer in biological systems are not fully understood. The traditional approach has been to use semiclassical transition-state theory. This theory cannot explain many experimental findings, however, so different approaches that emphasize the importance of quantum mechanics and dynamic effects should also be considered.
生物系统中氢转移的机制细节尚未完全了解。传统方法一直是使用半经典过渡态理论。然而，该理论无法解释许多实验结果，因此还应考虑强调量子力学和动态效应重要性的不同方法。
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