Ridley BA, Nivi B, Jacobson JM
The Media Laboratory, Massachusetts Institute of Technology, 20 Ames Street, Cambridge, MA 02139, USA.
Science. 1999 Oct 22;286(5440):746-749. doi: 10.1126/science.286.5440.746.
A solution of cadmium selenide nanocrystals was used to print inorganic thin-film transistors with field effect mobilities up to 1 square centimeter per volt second. This mobility is an order of magnitude larger than those reported for printed organic transistors. A field effect was achieved by developing a synthesis that yielded discretely sized nanocrystals less than 2 nanometers in size, which were free of intimately bound organic capping groups. The resulting nanocrystal solution exhibited low-temperature grain growth, which formed single crystal areas encompassing hundreds of nanocrystals. This process suggests a route to inexpensive, all-printed, high-quality inorganic logic on plastic substrates.
硒化镉纳米晶体溶液被用于印刷无机薄膜晶体管,其场效应迁移率高达每伏秒1平方厘米。该迁移率比已报道的印刷有机晶体管的迁移率大一个数量级。通过开发一种合成方法实现了场效应,该方法能产生尺寸小于2纳米的离散尺寸纳米晶体,且这些纳米晶体没有紧密结合的有机封端基团。所得的纳米晶体溶液表现出低温晶粒生长,形成了包含数百个纳米晶体的单晶区域。这一过程为在塑料基板上实现廉价的、全印刷的、高质量无机逻辑提供了一条途径。