Ong P K, Acree T E
Department of Food Science and Technology, Cornell University, New York State Agricultural Experiment Station, Geneva, New York 14456, USA.
J Agric Food Chem. 1999 Feb;47(2):665-70. doi: 10.1021/jf980452j.
GC/O analysis of canned lychees indicated that cis-rose oxide, linalool, ethyl isohexanoate, geraniol, furaneol, vanillin, (E)-2-nonenal, beta-damascenone, isovaleric acid, and (E)-furan linalool oxide were the most odor potent compounds detected in the fruit extracts. However, on the basis of calculated odor activity values (OAVs), cis-rose oxide, beta-damascenone, linalool, furaneol, ethyl isobutyrate, (E)-2-nonenal, ethyl isohexanoate, geraniol, and delta-decalactone were determined to be the main contributors of canned lychee aroma. When these results were compared with GC/O results of fresh lychees and Gewürztraminer wine, 12 common odor-active volatile compounds were found in all three products. These included cis-rose oxide, ethyl hexanoate/ethyl isohexanoate, beta-damascenone, linalool, ethyl isobutyrate, geraniol, ethyl 2-methylbutyrate, 2-phenylethanol, furaneol, vanillin, citronellol, and phenethyl acetate. On the basis of OAVs, cis-rose oxide had the highest values among the common odorants in the three products, indicating its importance to the aroma of both lychee fruit and Gewürztraminer wines. Other compounds that had significant OAVs included beta-damascenone, linalool, furaneol, ethyl hexanoate, and geraniol. This indicated that while differences exist in the aroma profile of lychee and Gewürztraminer, the common odorants detected in both fruit and wine, particularly cis-rose oxide, were responsible for the lychee aroma in Gewürztraminer wine. When headspace SPME was used as a rapid analytical tool to detect the levels of selected aroma compounds deemed important to lychee aroma in Gewürztraminer-type wines, cis-rose oxide, linalool, and geraniol were found to be at relatively higher levels in Gewürztraminers. No cis-rose oxide was detected in the control wines (Chardonnay and Riesling), while lower levels were detected in the Gewürztraminer-hybrid wine Traminette. Gewürztraminers produced in the Alsace region showed differences in the levels of the 3 monoterpenes when compared to those from New York State, which could be attributed to differences in viticultural and enological practices between regions.
对罐装荔枝的气相色谱 - 嗅闻分析表明,顺式玫瑰氧化物、芳樟醇、异己酸乙酯、香叶醇、呋喃酮、香草醛、(E)-2-壬烯醛、β-大马酮、异戊酸和(E)-呋喃芳樟醇氧化物是在水果提取物中检测到的气味活性最强的化合物。然而,根据计算出的气味活性值(OAVs),顺式玫瑰氧化物、β-大马酮、芳樟醇、呋喃酮、异丁酸乙酯、(E)-2-壬烯醛、异己酸乙酯、香叶醇和δ-癸内酯被确定为罐装荔枝香气的主要贡献成分。当将这些结果与新鲜荔枝和琼瑶浆葡萄酒的气相色谱 - 嗅闻结果进行比较时,在所有三种产品中发现了12种常见的气味活性挥发性化合物。这些化合物包括顺式玫瑰氧化物、己酸乙酯/异己酸乙酯、β-大马酮、芳樟醇、异丁酸乙酯、香叶醇、2-甲基丁酸乙酯、2-苯乙醇、呋喃酮、香草醛、香茅醇和苯乙酸乙酯。基于OAVs,顺式玫瑰氧化物在这三种产品的常见气味物质中具有最高的值,表明其对荔枝果实和琼瑶浆葡萄酒的香气都很重要。其他具有显著OAVs的化合物包括β-大马酮、芳樟醇、呋喃酮、己酸乙酯和香叶醇。这表明,虽然荔枝和琼瑶浆的香气特征存在差异,但在水果和葡萄酒中都检测到的常见气味物质,特别是顺式玫瑰氧化物,是琼瑶浆葡萄酒中荔枝香气的来源。当顶空固相微萃取被用作一种快速分析工具来检测对琼瑶浆型葡萄酒中荔枝香气重要的选定香气化合物的水平时,发现顺式玫瑰氧化物、芳樟醇和香叶醇在琼瑶浆中的含量相对较高。在对照葡萄酒(霞多丽和雷司令)中未检测到顺式玫瑰氧化物,而在琼瑶浆杂交品种特拉米内特中检测到的含量较低。与来自纽约州的琼瑶浆相比,阿尔萨斯地区生产的琼瑶浆在3种单萜类化合物的含量上存在差异,这可能归因于不同地区的葡萄栽培和酿酒工艺的差异。