以1-酰基苯并三唑作为区域选择性C-酰化试剂合成β-二羰基化合物。
Synthesis of beta-dicarbonyl compounds using 1-acylbenzotriazoles as regioselective C-acylating reagents.
作者信息
Katritzky AR, Pastor A
机构信息
Department of Chemistry, Center for Heterocyclic Compounds, University of Florida, Gainesville, Florida 32611-7200, USA.
出版信息
J Org Chem. 2000 Jun 16;65(12):3679-82. doi: 10.1021/jo991878f.
PMID:10864751
Abstract
1-Acylbenzotriazoles 1 are efficient C-acylation reagents for the regioselective conversion of ketone enolates 2 into beta-diketones 3.
摘要
1-酰基苯并三唑类化合物1是用于将酮烯醇盐2区域选择性转化为β-二酮3的高效C-酰化试剂。
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