通过钯介导的芳基-芳基偶联反应合成阿诺廷I。
Synthesis of arnottin I through a palladium-mediated aryl-aryl coupling reaction.
作者信息
Harayama T, Yasuda H, Akiyama T, Takeuchi Y, Abe H
机构信息
Faculty of Pharmaceutical Sciences, Okayama University, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2000 Jun;48(6):861-4. doi: 10.1248/cpb.48.861.
PMID:10866149
Abstract
6H-Dibenzo[b,d]pyran-6-one, 6H-benzo[d]naphtho[1,2-b]pyran-6-one, and their derivatives were prepared via the palladium mediated aryl-aryl coupling reaction of aryl ortho-halobenzoate. The short step synthesis of arnottin I(1) was achieved by this method.
摘要
6H-二苯并[b,d]吡喃-6-酮、6H-苯并[d]萘并[1,2-b]吡喃-6-酮及其衍生物是通过芳基邻卤苯甲酸酯的钯介导芳基-芳基偶联反应制备的。通过该方法实现了阿诺廷I(1)的短步骤合成。
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