Paixao JA, Sobral AJ, Rebanda NG
CEMDRX, Departamento de Fisica, Faculdade de Ciencias e Tecnologia, Universidade de Coimbra, P-3000 Coimbra, Portugal.
Acta Crystallogr C. 2000 Sep;56 (Pt 9):1136-8. doi: 10.1107/s0108270100008441.
The title compound, C(27)H(37)N, which is intended to be included in the structure of a sulfonamide porphyrin for the preparation of Langmuir-Blodgett films, consists of a dodecyl chain linked to an anthracene molecule through an aminomethyl group. The angle between the least-squares plane of the anthracene and the dodecyl chain is 11.44 (8) degrees. The molecules are arranged in zigzag layers head-to-head, with the hydrocarbon chains side-by-side. The structure is stabilized by C-H.pi interactions, the strongest having an H.centroid distance of 2.63 A.
标题化合物C(27)H(37)N旨在包含在用于制备朗缪尔-布洛杰特膜的磺酰胺卟啉结构中，它由通过氨甲基连接到蒽分子上的十二烷基链组成。蒽的最小二乘平面与十二烷基链之间的夹角为11.44(8)度。分子以头对头的方式排列成锯齿状层，烃链并排排列。该结构通过C-H·π相互作用得以稳定，最强的相互作用中H与质心的距离为2.63 Å。
