一种内消旋烷基取代的卟啉及其Ga(III)配合物的首次合成与X射线结构
First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex.
作者信息
Simkhovich L, Goldberg I, Gross Z
机构信息
Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Haifa.
出版信息
J Inorg Biochem. 2000 Jul 1;80(3-4):235-8. doi: 10.1016/s0162-0134(00)00077-5.
Abstract
The solvent-free condensation of heptafluorobutanal and pyrrole leads to the corresponding meso-alkyl-substituted corrole, which was metallated by gallium chloride to provide the first first-row non-transition-metal corrole. Both the ligand and the complex were characterized by X-ray crystallography.
摘要
七氟丁醛与吡咯的无溶剂缩合反应生成了相应的中位烷基取代的咕啉，该咕啉经氯化镓金属化得到了首个第一周期非过渡金属咕啉配合物。配体和配合物均通过X射线晶体学进行了表征。
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