Suppr超能文献

负载型TiO₂ + 紫外光在水溶液中对偶氮染料的光催化降解

Photocatalytic degradation of AZO dyes by supported TiO2 + UV in aqueous solution.

作者信息

Zhu C, Wang L, Kong L, Yang X, Wang L, Zheng S, Chen F, MaiZhi F, Zong H

机构信息

Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, People's Republic of China.

出版信息

Chemosphere. 2000 Aug;41(3):303-9. doi: 10.1016/s0045-6535(99)00487-7.

Abstract

The photocatalytic degradation performance of photocatalysts TiO2 supported on 13-X, Na-Y, 4A zeolites with different loading content was evaluated using the photocatalytic oxidation of dyes direct fast scarlet 4BS and acid red 3B in aqueous medium. The results showed that the best reaction dosage of TiO2-zeolite catalysts is about 2 g/l and the photocatalytic kinetics follows first order for all supported catalysts. The photocatalytic activity order of the three series catalysts is 13X type >Y type >4A type. The physical state of titanium dioxide on the supports is evaluated by X-ray photoelectron spectra (XPS), powder X-ray diffraction (XRD), BET, and FTIR.

摘要

采用在水介质中光催化氧化染料直接耐晒大红4BS和酸性红3B的方法,评价了负载于13-X、Na-Y、4A分子筛上不同负载量的光催化剂TiO₂的光催化降解性能。结果表明,TiO₂-沸石催化剂的最佳反应用量约为2 g/L,所有负载型催化剂的光催化动力学均符合一级反应。三个系列催化剂的光催化活性顺序为13X型>Y型>4A型。通过X射线光电子能谱(XPS)、粉末X射线衍射(XRD)、BET和傅里叶变换红外光谱(FTIR)对载体上二氧化钛的物理状态进行了评价。

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