Redeker K R, Wang N, Low J C, McMillan A, Tyler S C, Cicerone R J
Department of Earth System Science, Department of Chemistry, University of California, Irvine, CA 92697, USA.
Science. 2000 Nov 3;290(5493):966-9. doi: 10.1126/science.290.5493.966.
Methyl halide gases are important sources of atmospheric inorganic halogen compounds, which in turn are central reactants in many stratospheric and tropospheric chemical processes. By observing emissions of methyl chloride, methyl bromide, and methyl iodide from flooded California rice fields, we estimate the impact of rice agriculture on the atmospheric budgets of these gases. Factors influencing methyl halide emissions are stage of rice growth, soil organic content, halide concentrations, and field-water management. Extrapolating our data implies that about 1 percent of atmospheric methyl bromide and 5 percent of methyl iodide arise from rice fields worldwide. Unplanted flooded fields emit as much methyl chloride as planted, flooded rice fields.
甲基卤化物气体是大气中无机卤素化合物的重要来源,而无机卤素化合物又是许多平流层和对流层化学过程中的核心反应物。通过观测加利福尼亚州淹水稻田排放的氯甲烷、溴甲烷和碘甲烷,我们估算了水稻种植对这些气体大气收支的影响。影响甲基卤化物排放的因素包括水稻生长阶段、土壤有机含量、卤化物浓度和田间水管理。根据我们的数据推断,全球大气中约1%的溴甲烷和5%的碘甲烷来自稻田。未种植的淹水田与种植的淹水稻田排放的氯甲烷量相同。