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Studies on the synthesis of myriaporones: stereoselective synthesis of the C5-C13 fragment starting from D-glucose via regioselective reductive opening of methoxybenzylidene acetal.

作者信息

Zheng B Z, Yamauchi M, Dei H, Yonemitsu O

机构信息

Department of Chemistry, Okayama University of Science, Japan.

出版信息

Chem Pharm Bull (Tokyo). 2000 Nov;48(11):1761-5. doi: 10.1248/cpb.48.1761.

DOI:10.1248/cpb.48.1761
PMID:11086908
Abstract

A stereoselective synthesis is described of the C5-C13 fragment (4) of myriaporone 4 (1) starting from D-glucose by a coupling of the C5-C9 aldehyde (5), prepared using a regioselective reductive ring-opening of methoxybenzylidene acetal, with the C10-C13 iodoolefin (6).

摘要

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