Zha C S, Mao H, Hemley R J
Geophysical Laboratory and Center for High Pressure Research, Carnegie Institution of Washington, 5251 Broad Branch Road, NW, Washington, DC 20015, USA.
Proc Natl Acad Sci U S A. 2000 Dec 5;97(25):13494-9. doi: 10.1073/pnas.240466697.
We have studied the elasticity and pressure-density equation of state of MgO in diamond cells to 55 GPa and have doubled the previous pressure limit of accurate elasticity determinations for crystals. Integrating single-crystal velocity data from Brillouin scattering measurements and density data from polycrystalline x-ray diffraction, we obtained the three principal elastic tensor elements (C(11), C(12), and C(44)) and various secondary elasticity parameters, including single-crystal elastic anisotropy, Cauchy relation, aggregate sound velocities, and Poisson's ratio, as functions of pressure. The present study also provides a direct determination of pressure without recourse to any prior pressure standard, thus creating a primary pressure scale. The commonly used ruby fluorescence pressure scale has thus been improved to 1% accuracy by the new MgO scale.
我们在金刚石压腔中对氧化镁的弹性和压力-密度状态方程进行了研究,压力达到55吉帕,使此前晶体精确弹性测定的压力上限提高了一倍。通过整合布里渊散射测量得到的单晶速度数据和多晶X射线衍射得到的密度数据,我们获得了三个主要弹性张量元素(C(11)、C(12)和C(44))以及各种二级弹性参数,包括单晶弹性各向异性、柯西关系、集合声速和泊松比,它们都是压力的函数。本研究还提供了一种无需借助任何先前压力标准即可直接测定压力的方法,从而创建了一个原级压力标度。常用的红宝石荧光压力标度因此被新的氧化镁标度改进至1%的精度。