Collins P G, Hersam M, Arnold M, Martel R, Avouris P
IBM T. J. Watson Research Center, Yorktown Heights, New York 10598, USA.
Phys Rev Lett. 2001 Apr 2;86(14):3128-31. doi: 10.1103/PhysRevLett.86.3128.
We investigate the limits of high energy transport in multiwalled carbon nanotubes (MWNTs). In contrast to metal wires, MWNTs do not fail in the continuous, accelerating manner typical of electromigration. Instead, they fail via a series of sharp, equally sized current steps. We assign these steps to the sequential destruction of individual nanotube shells, consistent with the MWNT's concentric-shell geometry. Furthermore, the initiation of this failure is very sensitive to air exposure. In air failure is initiated by oxidation at a particular power, whereas in vacuum MWNTs can withstand much higher power densities and reach their full current carrying capacities.
我们研究了多壁碳纳米管(MWNTs)中高能输运的极限。与金属线不同,MWNTs不会以典型的电迁移连续加速方式失效。相反,它们通过一系列尖锐的、大小相等的电流阶跃失效。我们将这些阶跃归因于单个纳米管壳层的相继破坏,这与MWNT的同心壳层几何结构一致。此外,这种失效的起始对空气暴露非常敏感。在空气中,失效是由特定功率下的氧化引发的,而在真空中,MWNTs可以承受更高的功率密度并达到其全载流能力。