Lewis L A, Smithwick R W, Devault G L, Bolinger B, Lewis S A
Development Chemists, Analytical Chemistry Organization, Lockheed Martin Energy Systems, Inc., Oak Ridge, TN, USA.
J Forensic Sci. 2001 Mar;46(2):241-6.
Chemical processes involved in the development of latent fingerprints using the cyanoacrylate fuming method have been studied. Two major types of latent prints have been investigated-clean and oily prints. Scanning electron microscopy (SEM) has been used as a tool for determining the morphology of the polymer developed separately on clean and oily prints after cyanoacrylate fuming. A correlation between the chemical composition of an aged latent fingerprint, prior to development, and the quality of a developed fingerprint has been observed in the morphology. The moisture in the print prior to fuming has been found to be more important than the moisture in the air during fuming for the development of a useful latent print. In addition, the amount of time required to develop a high quality latent print has been found to be within 2 min. The cyanoacrylate polymerization process is extremely rapid. When heat is used to accelerate the fuming process, typically a period of 2 min is required to develop the print. The optimum development time depends upon the concentration of cyanoacrylate vapors within the enclosure.
使用氰基丙烯酸酯熏蒸法显现潜在指纹所涉及的化学过程已得到研究。已对两种主要类型的潜在指纹进行了调查——干净指纹和油性指纹。扫描电子显微镜(SEM)已被用作一种工具,用于确定氰基丙烯酸酯熏蒸后在干净指纹和油性指纹上分别形成的聚合物的形态。在形态学方面,已观察到显影前老化潜在指纹的化学成分与显影指纹质量之间的相关性。对于形成有用的潜在指纹而言,熏蒸前指纹中的水分比熏蒸期间空气中的水分更为重要。此外,已发现形成高质量潜在指纹所需的时间在2分钟以内。氰基丙烯酸酯聚合过程极其迅速。当使用加热来加速熏蒸过程时,通常需要2分钟来显影指纹。最佳显影时间取决于封闭环境中氰基丙烯酸酯蒸气的浓度。