Baldwin J E, Romeril S P, Lee V, Claridge T D
The Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QY, UK.
Org Lett. 2001 Apr 19;3(8):1145-8. doi: 10.1021/ol015646q.
[structure: see text]. The syntheses of the proposed structure of pyrinodemin A (1) and its cis double bond positional isomer (C15'-C16') in racemic form are described. The key reaction involved an intramolecular nitrone/double bond cycloaddition. Our results suggest that neither 1 nor its double positional isomer is the correct structure of pyrinodemin A
[结构：见正文]。描述了外消旋形式的拟议的匹利诺德明A（1）及其顺式双键位置异构体（C15'-C16'）结构的合成。关键反应涉及分子内硝酮/双键环加成。我们的结果表明，1及其双键位置异构体都不是匹利诺德明A的正确结构。
