手性二氧杂环丙烷对末端烯烃的对映选择性环氧化反应。
Enantioselective epoxidation of terminal olefins by chiral dioxirane.
作者信息
Tian H, She X, Xu J, Shi Y
机构信息
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
出版信息
Org Lett. 2001 Jun 14;3(12):1929-31. doi: 10.1021/ol010066e.
PMID:11405747
Abstract
[see reaction]. This paper describes an enantioselective epoxidation of terminal olefins using chiral ketone 3 as catalyst and Oxone as oxidant. Up to 85% ee has been obtained.
摘要
[见反应]。本文描述了使用手性酮3作为催化剂和过一硫酸氢钾复合盐作为氧化剂对末端烯烃进行对映选择性环氧化反应。已获得高达85%的对映体过量值。
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