Blake D F, Freund F, Krishnan K F, Echer C J, Shipp R, Bunch T E, Tielens A G, Lipari R J, Hetherington C J, Chang S
NASA Ames Research Center, Moffett Field, California 94035, USA.
Nature. 1988 Apr 14;332(6165):611-3. doi: 10.1038/332611a0.
Microscopic diamond was recently discovered in oxidized acid residues from several carbonaceous chondrite meteorites (for example, the C delta component of the Allende meteorite). Some of the reported properties of C delta seem in conflict with those expected of diamond. Here we present high spatial resolution analytical data which may help to explain such results. The C delta diamond is an extremely fine-grained (0.5-10 nm) single-phase material, but surface and interfacial carbon atoms, which may comprise as much as 25% of the total, impart an 'amorphous' character to some spectral data. These data support the proposed high-pressure conversion of amorphous carbon and graphite into diamonds due to grain-grain collisions in the interstellar medium although a low-pressure mechanism of formation cannot be ruled out.
最近在几块碳质球粒陨石(例如,阿连德陨石的Cδ组分)的氧化酸残渣中发现了微观钻石。一些报道的Cδ的性质似乎与钻石预期的性质相冲突。在此,我们展示了高空间分辨率分析数据,这可能有助于解释此类结果。Cδ钻石是一种极其细粒度(0.5 - 10纳米)的单相材料,但表面和界面碳原子可能占总数的25%之多,这给一些光谱数据赋予了“非晶态”特征。这些数据支持了由于星际介质中的颗粒 - 颗粒碰撞而将非晶碳和石墨高压转化为钻石的提议,尽管不能排除低压形成机制。