Ryan M A, Lewis N S
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA.
Enantiomer. 2001;6(2-3):159-70.
Arrays of broadly responsive vapor detectors can be used to detect, identify, and quantify vapors and vapor mixtures. One implementation of this strategy involves the use of arrays of chemically-sensitive resistors made from conducting polymer composites. Sorption of an analyte into the polymer composite detector leads to swelling of the film material. The swelling is in turn transduced into a change in electrical resistance because the detector films consist of polymers filled with conducting particles such as carbon black. The differential sorption, and thus differential swelling, of an analyte into each polymer composite in the array produces a unique pattern for each different analyte of interest, Pattern recognition algorithms are then used to analyze the multivariate data arising from the responses of such a detector array. Chiral detector films can provide differential detection of the presence of certain chiral organic vapor analytes. Aspects of the spaceflight qualification and deployment of such a detector array, along with its performance for certain analytes of interest in manned life support applications, are reviewed and summarized in this article.
具有广泛响应能力的蒸汽探测器阵列可用于检测、识别和量化蒸汽及蒸汽混合物。该策略的一种实现方式涉及使用由导电聚合物复合材料制成的化学敏感电阻器阵列。分析物吸附到聚合物复合材料探测器中会导致薄膜材料膨胀。由于探测器薄膜由填充有导电颗粒(如炭黑)的聚合物组成,这种膨胀进而转化为电阻变化。分析物在阵列中每个聚合物复合材料中的差异吸附以及由此产生的差异膨胀,会为每种感兴趣的不同分析物产生独特的模式,然后使用模式识别算法来分析由这种探测器阵列的响应产生的多变量数据。手性探测器薄膜可以提供对某些手性有机蒸汽分析物存在的差异检测。本文对这种探测器阵列的航天资格认证和部署方面,以及其在载人生命支持应用中对某些感兴趣分析物的性能进行了综述和总结。