Kajtár-Peredy M, Tömösközi I, Gács-Baitz E
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Budapest.
Nucleosides Nucleotides Nucleic Acids. 2001 Sep;20(9):1615-23. doi: 10.1081/NCN-100105899.
Synthesis and stereochemical characterization of enantiomerically pure nucleoside-phosphorothioselenoates are reported. The effects of solvent and temperature on the vicinal carbon-phosphorus couplings are described and the results are interpreted in terms of conformational changes influenced by stacking interactions between the bases and the phenyl rings.
