氯（3,6,13,16-四乙基-2,7,12,17-四甲基卟吩并四氮杂卟啉合κ4N）铁（III）氯仿溶剂化物
Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato-kappa4N)iron(III) chloroform solvate.
作者信息
Ohgo Y, Neya S, Ikeue T, Funasaki N, Nakamura M
机构信息
Department of Chemistry, Toho University School of Medicine, 5-21-16 Omorinishi, Ota-ku, Tokyo 143-8540, Japan.
出版信息
Acta Crystallogr C. 2001 Sep;57(Pt 9):1046-7. doi: 10.1107/s0108270101009842. Epub 2001 Sep 11.
The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo[16.2.1.1(2,5).1(8,11).1(12,15)]tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C(33)H(37)N(4))Cl].CHCl(3), reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central Fe(III) atom from the least-squares plane of the C(20)N(4) core is 0.594 (1) A. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) A; Fe-Cl 2.232 (1) A.
标题配合物氯[3,10,13,20-四乙基-4,9,14,19-四甲基五环[16.2.1.1(2,5).1(8,11).1(12,15)]二十四碳-2,4,6,8(23),9,12,14,16,18(21),19-癸烯]铁(III)氯仿溶剂合物，[Fe(C₃₃H₃₇N₄)Cl]·CHCl₃的X射线晶体学分析表明，其具有扭曲的大环骨架，核心为稍有畸变的矩形金字塔结构，中心Fe(III)原子偏离C₂₀N₄核心的最小二乘平面的距离为0.594(1) Å。一些重要的键长如下：Fe-N为2.019(3)、2.026(3)、2.028(3)和2.034(3) Å；Fe-Cl为2.232(1) Å。
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