（5,10,15,20-四苯基卟啉合-κ4N）双（L-缬氨酸-κN甲酯）铁（III）三氟甲磺酸盐二氯甲烷溶剂化物
(5,10,15,20-Tetraphenylporphyrinato-kappa4N)bis(L-valine-kappaN methyl ester)iron(III) trifluoromethylsulfonate dichloromethane solvate.
作者信息
Kobeissi Marwan, Toupet Loic, Simonneaux Gerard
机构信息
Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes I, Campus de Beaulieu, 35042 Rennes Cedex, France.
出版信息
Acta Crystallogr C. 2002 Aug;58(Pt 8):m443-4. doi: 10.1107/s0108270102011605. Epub 2002 Jul 20.
PMID:12154288
Abstract
The title compound, Fe(C(44)H(28)N(4))(C(6)H(13)NO(2))(2).CH(2)Cl(2), is the first amino ester complex of iron porphyrins to be investigated using X-ray diffraction and it can be considered as a model complex of cytochrome f. The Fe atom is six-coordinate to four N atoms of the porphyrin ring and to two N atoms of the axial amino ester ligands.
摘要
标题化合物Fe(C₄₄H₂₈N₄)(C₆H₁₃NO₂)₂·CH₂Cl₂是首个采用X射线衍射研究的铁卟啉氨基酯配合物，可被视为细胞色素f的模型配合物。铁原子与卟啉环的四个氮原子以及轴向氨基酯配体的两个氮原子形成六配位。
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