化学固定二氧化碳：铬（III）席夫碱配合物作为二氧化碳与环氧化合物偶联的高效催化剂。 - Suppr

Chemical CO(2) fixation: Cr(III) salen complexes as highly efficient catalysts for the coupling of CO(2) and epoxides.

作者信息

Paddock R L, Nguyen S B

机构信息

Department of Chemistry, Institute for Environmental Catalysis, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA.

出版信息

J Am Chem Soc. 2001 Nov 21;123(46):11498-9. doi: 10.1021/ja0164677.

DOI:10.1021/ja0164677

PMID:11707136

Abstract

摘要

相似文献

Chemical CO(2) fixation: Cr(III) salen complexes as highly efficient catalysts for the coupling of CO(2) and epoxides.化学固定二氧化碳：铬（III）席夫碱配合物作为二氧化碳与环氧化合物偶联的高效催化剂。

J Am Chem Soc. 2001 Nov 21;123(46):11498-9. doi: 10.1021/ja0164677.

CO2 copolymers from epoxides: catalyst activity, product selectivity, and stereochemistry control.环氧乙烷共聚二氧化碳：催化剂活性、产物选择性和立体化学控制。

Acc Chem Res. 2012 Oct 16;45(10):1721-35. doi: 10.1021/ar300035z. Epub 2012 Aug 2.

Highly efficient metal(iii) porphyrin and salen complexes for the polymerization of rac-lactide under ambient conditions.高效金属（III）卟啉和席夫碱配合物在环境条件下用于 rac-丙交酯的聚合。

Dalton Trans. 2019 Mar 5;48(10):3223-3230. doi: 10.1039/c8dt04699a.

Polyolefin-supported recoverable/reusable Cr(III)-salen catalysts.聚烯烃负载的可回收/可重复使用的 Cr(III)-salen 催化剂。

J Org Chem. 2011 Jan 21;76(2):523-33. doi: 10.1021/jo102044m. Epub 2010 Dec 30.

Mechanistic insight into the initiation step of the coupling reaction of oxetane or epoxides and CO2 catalyzed by (salen)CrX complexes.对（salen）CrX配合物催化氧杂环丁烷或环氧化物与二氧化碳偶联反应引发步骤的机理洞察。

Inorg Chem. 2008 Nov 3;47(21):10000-8. doi: 10.1021/ic801231p. Epub 2008 Sep 27.

Ionic Polymer Microspheres Bearing a Co(III) -Salen Moiety as a Bifunctional Heterogeneous Catalyst for the Efficient Cycloaddition of CO2 and Epoxides.负载Co(III)-Salen部分的离子聚合物微球作为二氧化碳与环氧化物高效环加成反应的双功能多相催化剂

Chemistry. 2016 Jun 6;22(24):8368-75. doi: 10.1002/chem.201600755. Epub 2016 Apr 26.

Self-assembly approach toward chiral bimetallic catalysts: bis-urea-functionalized (salen)cobalt complexes for the hydrolytic kinetic resolution of epoxides.自组装方法制备手性双金属催化剂：双脲基功能化（席夫碱）钴配合物用于环氧化物的水解动力学拆分。

Chemistry. 2011 Feb 11;17(7):2236-45. doi: 10.1002/chem.201002600. Epub 2011 Jan 10.

(Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides: role of the initiator and cocatalyst.用于二氧化碳与环氧化合物共聚的（Salen）CrIII X催化剂：引发剂和助催化剂的作用

Inorg Chem. 2004 Mar 22;43(6):1831-3. doi: 10.1021/ic0352856.

Enhanced cooperativity through design: pendant Co(III)--salen polymer brush catalysts for the hydrolytic kinetic resolution of epichlorohydrin (salen=N,N'-bis(salicylidene)ethylenediamine dianion).通过设计增强协同性：用于环氧氯丙烷水解动力学拆分的悬挂式Co(III)-salen聚合物刷催化剂（salen = N,N'-双（水杨醛）乙二胺二价阴离子）

Chemistry. 2008;14(24):7306-13. doi: 10.1002/chem.200800532.

Ring-expanding olefin metathesis: a route to highly active unsymmetrical macrocyclic oligomeric co-salen catalysts for the hydrolytic kinetic resolution of epoxides.扩环烯烃复分解反应：一种用于环氧化合物水解动力学拆分的高活性不对称大环低聚共双水杨醛催化剂的合成途径。

J Am Chem Soc. 2007 Feb 7;129(5):1105-12. doi: 10.1021/ja0641406.

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Bifunctional MOFs in Heterogeneous Catalysis.双功能金属有机框架材料在多相催化中的应用

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Direct coupling of CO with epoxides catalyzed by lanthanum(III) supported on magnetic mesoporous organosilica nanoparticles.磁性介孔有机硅纳米粒子负载镧(III)催化的 CO 与环氧化物的直接偶联。

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Atmospheric-Pressure Conversion of CO to Cyclic Carbonates over Constrained Dinuclear Iron Catalysts.受限双核铁催化剂上CO常压转化为环状碳酸酯

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Functional Porous Ionic Polymers as Efficient Heterogeneous Catalysts for the Chemical Fixation of CO under Mild Conditions.功能性多孔离子聚合物作为温和条件下CO化学固定的高效多相催化剂

Polymers (Basel). 2022 Jun 29;14(13):2658. doi: 10.3390/polym14132658.

Highly efficient Co centers functionalized by nitrogen-doped carbon for the chemical fixation of CO.氮掺杂碳功能化的高效钴中心用于CO的化学固定

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Nitrogen-decorated, porous carbons derived from waste cow manure as efficient catalysts for the selective capture and conversion of CO.以废弃牛粪为原料制备的氮修饰多孔碳作为高效催化剂用于CO的选择性捕获与转化。

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Chromium-Salophen as a Soluble or Silica-Supported Co-Catalyst for the Fixation of CO Onto Styrene Oxide at Low Temperatures.铬-萨罗芬作为可溶性或负载于二氧化硅上的助催化剂用于低温下将一氧化碳固定到环氧苯乙烷上。

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Conversion of CO into Chloropropene Carbonate Catalyzed by Iron (II) Phthalocyanine Hypercrosslinked Porous Organic Polymer.由铁(II)酞菁超交联多孔有机聚合物催化将 CO 转化为氯丙烯碳酸酯。

Molecules. 2020 Oct 9;25(20):4598. doi: 10.3390/molecules25204598.

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Chemical CO(2) fixation: Cr(III) salen complexes as highly efficient catalysts for the coupling of CO(2) and epoxides.

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